梁子骐

梁子骐

教授        

电话/传真:(021) 31243636   

Email:zqliang@fudan.edu.cn      

地址:上海市淞沪路2005号复旦大学江湾校区先进材料楼503室       

课题组主页:www.opv-te.fudan.edu.cn

教育和科研背景

  • 2012年9月--至今     复旦大学材料科学系 教授 博士生导师

  • 2008年6月-2012年6月  美国国家可再生能源实验室  博士后、科学家III

  • 2006年5月-2008年5月  英国剑桥大学 博士后

  • 2006年春季        美国宾夕法尼亚州立大学材料科学与工程系高分子科学专业  博士

  • 2002年夏季        美国加州大学河滨分校化学系 硕士

  • 1999年春季        华东理工大学/上海交通大学 高分子材料科学与工程系  本科/硕士研究生

奖励和荣誉

  • 美国宾夕法尼亚州立大学(研究生)杰出科研奖

  • 上海市浦江人才计划入选者

  • 上海市优秀学术带头人

教学

  • 本科生:材料科学前沿讲座(Frontiers in Materials Science,校优秀全英文课程)MATE130052

  • 博士研究生:有机半导体材料与电子器件(Organic Semiconductors and Electronic  Devices)MATE820012

主要研究领域

 从事有机/钙钛矿半导体材料光+热—电能源转换研究,主要开展以下工作:

(1)π-共轭高分子:设计、合成、功能与器件;

(2)光电能量转换:有机/钙钛矿太阳能电池及其关键物理化学问题研究;

(3)热电能量转换:有机半导体材料、有机/无机纳米复合材料及元件的热电性能研究。

科研论文及著作

70. J. Xie, W. Lin, G. C. Bazan, T. Pullerits, K. Zheng,* Z. Liang,* N-Doping of Nonfullerene Bulk-Hetrojunction Organic Solar Cells Strengthens Photogeneration and Exciton Dissociation. J. Mater. Chem. A 10, 18845−18855 (2022).

69. S. Yu, J. Meng, Q. Pan, Q. Zhao, T. Pullerits, Y. Yang,* K. Zheng,* Z. Liang,* Imaidazole Additives in 2D Halide Perovskites: Impacts of −CN versus −CH3 Substituents Reveal the Mediation of Crystal Growth by Phase Buffering. Energy Environ. Sci. 15, 3321−3330 (2022).

68. R. Chen, Y. Yan, J. Tang, Q. Yao,* L. Chen, Z. Liang,* Top-Down Diffusion Doping of Tin Halide Perovskite Substantially Enhances Electrical Conductivity and Thermoelectrical Power Factor. Small Sci. 2, 2200004 (2022).

67. J. Ji, L. Zhu, X. Xiong, K. Zheng, F. Liu, Z. Liang,* Developing Y-Branched Polymer Acceptor with 3D Architectures to Reconcile Between Crystallinity and Miscibility Yielding >15% Efficient All-Polymer Solar Cells. Adv. Sci. 9, 2200864 (2022).

66. K. Ba, D. Pu, X. Yang, T. Ye, J. Chen, X. Wang, T. Xiao, T. Duan,* Y. Sun, B. Ge, P. Zhang, Z, Liang,* Z. Sun,* Billiard Catalysis at Ti3C2Tx MXene/MAX Heterostructure for Efficient Nitrogen Fixation. Appl. Catal. B Environ. 317, 121755 (2022).

65. J. Tang, J. Ji, R. Chen, Y. Yan, Y. Zhao, Z. Liang,* Achieving Efficient p-Type Organic Thermoelectrics by Modulation of Acceptor Unit in Photovoltaic π-Conjugated Copolymers. Adv. Sci. 9, 2103646 (2022).

64. J. Sun, S. Yang,* J. Wu, X. He, Y. Zhang, J. Ji, C. Zhang, Z. Liang,* In-Situ Electro-Polymerization of Fluorescent Electrochromic Thin Films Based on Charge-Transfer Complexes. Chem. Eng. J. 428, 132625 (2022).

63. Y. Yan, Y. Yang,* M. Abdellah, M. Liang, K. Zheng,* T. Pullerits, Z. Liang,* Implementing An Intermittent Spin-Coating Strategy to Enable Bottom-up Crystallization in Layered Halide Perovskites. Nat. Commun. 12, 6603 (2021).

62. S. Yu, M. Abdellah, T. Pullerits, K. Zheng,* Z. Liang,* Asymmetric Spacer in Dion-Jacobson Halide Perovskites Induces Staggered Alignment to Direct Out-of-Plane Carrier Tansport and Enhance Ambient Stability Simultaneously. Adv. Funct. Mater. 31, 2104342 (2021).

61. J. Ji, J. Xie, J. Tang, K. Zheng,* Z. Liang,* Developing Halogen-Free Polymer Donors for Efficient Nonfullerene Organic Solar Cells by Addition of Highly Electron-Deficient Diketopyrrolopyrrole Unit. Sol. RRL 5, 2100142 (2021).

60. R. Chen, J. Tan, Y. Yan, Z. Liang,* Effective n-Type Doping of SWCNTs Mediated by Solvent to Achieve Superior Power Factor. Adv. Mater. Technol. 2000288 (2020).

59. Z. Wang, J. Ji, W. Lin, Y. Yao, Zheng,* Z. Liang,* Mechanistic Investigation into Dynamic Function of Third-Component Incorporated in Ternary Near-Infrared Nonfullerene Organic Solar Cells. Adv. Funct. Mater. 30, 2001564 (2020).

58. Y. Yan, T. Pullerits, K. Zheng,* Z. Liang,* Advancing Tin Halide Perovskites: Strategies toward the ASnX3 Paradigm for Efficient andDurable Optoelectronics. ACS Energy Lett. 5, 2052−2086 (2020).

57. J. Tang, R. Chen, L. Chen, G. C. Bazan, Z. Liang,* Semiconducting Polymer Contributes Favorably to the Seebeck Coefficient in Multi-component, High-Performance n-Type Thermoelectric Nanocomposites. J. Mater. Chem. A 8, 9797−9805 (2020).

56. S. Yu, Y. Yan, M. Abdellah, T. Pullerits, K. Zheng,* Z. Liang,* Non-Confinement Structure Revealed in Dion-Jacobson Type Quasi-2D Perovskite Expedites Interlayer Charge Transport. Small 15, 1905081 (2019).

55. Y. Yan, S. Yu, A. Honarfar, T. Pullerits, K. Zheng,* Z. Liang,* Benefiting from Spontaneously Generated 2D/3D Bulk-Heterojunctions in Ruddlesden−Popper Perovskite by Incorporation of S-Bearing Spacer Cation. Adv. Sci. 6, 1900548 (2019).

54. Z. Liang,* L. Chen,* G. C. Bazan,* Editorial in Organic and Hybrid Thermoelectrics Special Issue, Adv. Electron. Mater. 5, 1900650 (2019).

53. J. Tang, Y. Chen, S. R. McCuskey, L. Chen,* G. C. Bazan,* Z. Liang,* Recent Advances in n-Type Thermoelectric Nanocomposites. Adv. Electron. Mater. 5, 1800943 (2019).

52. X. Liu, Y. Yan, Y. Yao, A. Honarfar, K. Zheng*, Z. Liang,* Unveiling Excitonic Dynamics in High-Efficiency Nonfullerene Organic Solar Cells to Direct Morphological Optimization for Suppressing Charge Recombination. Adv. Sci. 6, 1802103 (2019).

51. S. Yu, Y. Yan, Y. Chen, P. Chábera, K. Zheng,* Z. Liang,* Enabling Room-Temperature Processed Highly Efficient 2D Ruddlesden−Popper Perovskite Solar Cells with Eliminated Hysteresis by Synergistic Exploitation of Additive and Solvent. J. Mater. Chem. A 7, 2015–2021 (2019).

50. Y. Yan, Q. Wu, Y. Zhao, S. Chen, S. Hu, J. Zhu, J. Huang,* Z. Liang,* Air-Stable and Self-Driven Perovskite Photodiodes with High ON/OFF Ratio and Swift Photoresponse. Small 1802764 (2018).

49. X. Gao, M. He, B. Liu, J. Hu, Y. Wang,* Z. Liang,* J. Zhou*, Topological Design of Inorganic-Organic Thermoelectric Nanocomposites Based on ¢Electron-Percolation Phonon-Insulator¢ Concept. ACS Appl. Energy Mater. 1, 2927–2933 (2018).

48. Y. Chen, Y. Sun, J. Peng, P. Chábera, A. Honarfar, K. Zheng,* Z. Liang,* Composition Engineering in Pb-Sn Alloyed Two-Dimensional Perovskite Solar Cells. ACS Appl. Mater. Interfaces 10, 21343–21348 (2018).

47. Y. Chen, M. He, J. Tang, G. C. Bazan, Z. Liang,* Flexible Thermoelectric Generators with Ultra-High Output Power Enabled by Magnetic Field Aligned Metallic Nanowires. Adv. Electron. Mater. 1800200 (2018).

46. Y. Chen, S. Yu, Y. Sun, Z. Liang,* Phase Engineering in Quasi-2D Ruddlesden–Popper Perovskites. J. Phys. Chem. Lett. 9, 2627–2631 (2018).

45. X. Liu, Y. Yan, Y. Yao,* Z. Liang,* Ternary Blend Strategy for Achieving High-Efficiency Organic Solar Cells with Nonfullerene Acceptors Involved. Adv. Funct. Mater. 28, 1802004 (2018).

44. K. Zheng,* Y. Chen, Y. Sun, J. Chen, P. Chábera, R. Schaller, M. J. Al-Marri, S. E. Canton, Z. Liang,* T. Pullerits,* Inter-Phase Charge and Energy Transfer in Ruddlesden–Popper 2D Perovskites: Critical Role of the Spacing Cations. J. Mater. Chem. A 8, 6244–6250 (2018).

43. Y. Chen, Y. Sun, J. Peng, K. Zheng, Z. Liang,* Two-Dimensional Ruddlesden−Popper Perovskites for Optoelectronics. Adv. Mater. 30, 1703487 (2018).

42. Y. Jin, Y. Sun, K. Wang, Y. Chen, Z. Liang, Y. Xu, F. Xiao, Long-Term Stable Silver Nanowire Transparent Composite as Bottom Electrode for Perovskite Solar Cells. Nano Res. 11, 1998–2011 (2018).

41. M. He, X. Gao, B. Liu, J. Zhou,* Z. Liang,* Ultra-High Electrical Conductivity and Superior Bendability Simultaneously Enabled in Ag Nanowire Based Nanocomposites. RSC Adv. 7, 44254-44258 (2017).

40. Y. Jin, Z. Chen, M. Xiao, J. Peng, B. Fan, L. Ying, G. Zhang, X.-F. Jiang, Q. Yin, Z. Liang, F. Huang, Y. Cao, Thick Film Polymer Solar Cells Based on Naphtho[1,2-c:5,6-c]bis[1,2,5]thiadiazole Conjugated Polymers with Efficiency over 11%. Adv. Energy Mater. 7, 1700944 (2017).

39. X. Liu, J. Wang, J. Peng, Z. Liang,* 2D/1A Strategy to Regulate Film Morphology for Highly Efficient and Stable Nonfullerene Organic Solar Cells. Macromolecules 50, 6954-6960 (2017).

38. J. Peng, Y. Chen, K. Zheng,* T. Pullerits, Z. Liang,* Insights into Charge Carrier Dynamics in Organo-Metal Halide Perovskites: From Neat Films to Solar Cells. Chem. Soc. Rev. 46, 5714-5729 (2017).

37. S. Chen, S. Yang, H. Sun, L. Zhang, J. Peng, Z. Liang, Z. S. Wang, Enhanced Interfacial Electron Transfer of Inverted Perovskite Solar Cells by Introduction of CoSe into the Electron-Transporting Layer. J. Power Sources 353, 123-130 (2017).

36. J. Wang, J. Peng, X. Liu, Z. Liang,* Efficient and Stable Ternary Organic Solar Cells Based on Two Planar Nonfullerene Acceptors with Tunable Crystallinity and Phase Miscibility. ACS Appl. Mater. Interfaces 9, 20704-20710 (2017).

35. Y. Sun. D. Chen, Z. Liang,* Two-Dimensional MXenes for Energy Storage and Conversion Applications. Mater. Today Energy 5, 22–36 (2017).

34. J. Sun,* H. Sun, Z. Liang,* Nanomaterials in Electrochemiluminescence Sensors. ChemElectroChem 4, 1651-1662 (2017).

33. Y. Chen, Y. Sun, J. Peng, W. Zhang, X. Su, K. Zheng, T. Pullerits, Z. Liang,* Tailoring Organic Cation of Two-Dimensional Air-Stable Organometal Halide Perovskites for Highly Efficient Planar Solar Cells. Adv.Energy Mater. 7, 1700162 (2017).

32. Y. Sun, J. Peng, Y. Chen, Y. Yao, Z. Liang,* Triple-Cation Mixed-Halide Perovskites: Fabrication of Efficient, Annealing-Free, Air-Stable Solar Cells Enabled by Pb(SCN)2 Additive. Sci. Rep. 7, 46193 (2017).

31. M. Li, K. Gao, X. Wan, Q. Zhang, B. Kan, R. Xia, F. Liu, X. Yang, H. Feng, W. Ni, Y. Wang, J. Peng, H. Zhang, Z. Liang, H.-L. Yip, X. Peng, Y. Cao, Y. Chen, Solution-Processed Organic Tandem Solar Cells with Power Efficiencies >12%. Nat. Photon. 11, 85-90 (2017).

30. Y. Chen, M. He, B. Liu, G. C. Bazan,* J. Zhou,* Z. Liang,* Bendable n-Type Metallic Nanocomposites with Large Thermoelectric Power Factor. Adv. Mater. 29, 1604752 (2017).

29. J. Peng, Y. Sun, Y. Chen, Y. Yao,* Z. Liang,* Light and Thermally Induced Evolutional Charge Transport in CH3NH3PbI3 Perovskite Solar Cells. ACS Energy Lett. 1, 1000-1006 (2016).

28. J. Wang, J. Peng, Y. Sun, X. Liu, Y. Chen, Z. Liang,* FAPbCl3 Perovskite as Alternative Interfacial Layer for Highly Efficient and Stable Polymer Solar Cells. Adv. Electron. Mater. 2, 1600329 (2016).

27. J. Wang, Z. Liang,* Synergetic Solvent Engineering of Film Nanomorphology to Enhance Planar Perylene Diimide Based Organic Photovoltaics. ACS Appl. Mater. Interfaces 8, 22418-22424 (2016).

26. J. Sun, Z. Liang,* Swift Electrofluorochromism of Donor-Acceptor Conjugated Polytriphenylamines. ACS Appl. Mater. Interfaces 8, 18301-18308 (2016).

25. J. Wang, L. Kong, Z. Liang,* Fine Control of Side Chains in Random π-Conjugated Terpolymers for Organic Photovoltaics. Macromol. Chem. Phys. 217, 1513-1520 (2016).

24. D. Chen, Y. Zhao, Y. Chen, T. Lu, Y. Wang,* J. Zhou,* Z. Liang,* Thermoelectric Enhancement of Ternary Copper Chalcogenide Nanocrystals by Magnetic Nickel Doping. Adv. Electron. Mater. 2, 1500473 (2016).

23. J. Sun, Y. Chen, Z. Liang,* Electroluminochromic Materials and Devices. Adv. Funct. Mater. 26, 2783–2799 (2016).

22. Y. Chen, M. He, J. Peng, Y. Sun, Z. Liang,* Structure and Growth Control of Organic-Inorganic Halide Perovskites for Optoelectronics: From Polycrystalline Films to Single Crystals. Adv. Sci. 3, 1500392 (2016).

21. J. Peng, Y. Chen, X. Zhang, A. Dong, Z. Liang,* Solid-State Ligand-Exchange Fabrication of CH3NH3PbI3 Capped PbS Quantum Dot Solar Cells. Adv. Sci. 3, 1500432 (2016).

20. J. Peng, X. Chen, Y. Chen, O. Sandberg, R. Österbacka,* Z. Liang,* Transient Extraction of Holes and Electrons Separately Reveals the Transport Dynamics in Organic Photovoltaics. Adv. Electron. Mater. 2, 1500333 (2016).

19. B. Li, Y. Chen, Z. Liang,* D. Gao,* W. Huang,* Interfacial Engineering by Using Self-Assembled Monolayer in Mesoporous Perovskite Solar Cell. RSC Adv. 5, 94290-94295 (2015).

18. M. He, Y. Zhao, B. Wang, Q. Xi, J. Zhou,* Z. Liang,* 3D Printing Fabrication of Amorphous Thermoelectric Materials with Ultralow Thermal Conductivity. Small 11, 5889-5894 (2015).

17. Y. Zhang, J. Du, X. Wu, G. Zhang, Y. Chu, D. Liu, Y. Zhao,* Y. Zhao,* Z. Liang,* J. Huang,* Ultrasensitive Phototransistors Based on Island-Structured CH3NH3PbI3 Thin Films. ACS Appl. Mater. Interfaces 7, 21634-21638 (2015).

16. K. Wang, Z. Liang, X. Wang, X. Cui, Lead Replacement in CH3NH3PbI3 Perovskites. Adv. Electron. Mater. 1, 1500089 (2015).

15. J. Peng, Y. Chen, X. Wu,Q. Zhang, X. Chen, Y. Chen,* J. Huang,* Z. Liang,* Correlating Molecular Structures with Transport Dynamics in High-Efficiency Small Molecule Organic Photovoltaics. ACS Appl. Mater. Interfaces 7, 13137-13141 (2015).

14. Y. Chen, B. Li, W. Huang, D. Gao,* Z. Liang,* Efficient and Reproducible CH3NH3PbI3−x(SCN)x Perovskite Based Planar Solar Cells. Chem. Commun.51, 11997-11999 (2015).

13. M. He, Y. Chen, H. Liu, J. Wang, X. Fang, Z. Liang,* Chemical Decoration of CH3NH3PbI3 Perovskite with Graphene Oxides for Photodetector Applications. Chem. Commun.51, 9659-9661 (2015).

12. D. Chen, Y. Zhao, Y. Chen, B. Wang, Y. Wang, J. Zhou,* Z. Liang,* Hot-Injection Synthesis of Cu-doped Cu2ZnSnSe4 Nanocrystals to Reach Thermoelectric Figure of Merit of 0.70. ACS Appl. Mater. Interfaces 7, 24403-24408 (2015).

11. X. Chen, Z. He, Y. Hu, Y. He, H. Peng, Z. Liang,* Tunable Exciton Dissociation at the Organic/Metal Electrode Interface. J. Phys. Chem. C119, 7039-7046 (2015).

10. Y. Chen, Y. Zhao, Z. Liang,* Nonvolatile Chlorinated Additives Adversely Influence CH3NH3PbI3 Based Planar Solar Cells. J. Mater. Chem. A3, 9137-9140 (2015).

9. Y. Chen, J. Peng, D. Su, X. Chen, Z. Liang,* Efficient and Balanced Charge Transport Revealed in Planar Perovskite Solar Cells. ACS Appl. Mater. Interfaces7, 4471-4475 (2015).

8. Y. Chen, Y. Zhao, Z. Liang,* Non-Thermal Annealing Fabrication of Efficient Planar Perovskite Solar Cells with Inclusion of NH4Cl. Chem. Mater.27, 1448-1451 (2015).

7. M. He, K. Song, H. Mo, J. Li, D. Pan, Z. Liang,* Progress on Photosensitive Resins for 3D Printing. J. Funct. Polym. 28, 102-108 (2015).

6. D. Su, Y. Yao, Y. Chen, J. Peng, Z. Liang,* Conjugated Polymers Based Chemical and Biological Sensors” in Smart Nanomaterials for Sensors and Transducers. World Scientific Publishers (2016).

5. D. Chen, Y. Zhao, Y. Chen, B. Wang, H. Chen, J. Zhou, Z. Liang,* One-Step Chemical Synthesis of ZnO/Graphene Oxide Molecular Hybrids for High-Temperature Thermoelectric Applications. ACS Appl. Mater. Interfaces 7, 3224-3230 (2015).

4. Y. Chen, Y. Zhao, Z. Liang,* Solution Processed Organic Thermoelectrics: Towards Flexible Thermoelectric Modules. Energy Environ. Sci. 8, 401-422 (2015).

3. Q. Zhang, B. Kan, G. Long, X. Wan, F. Liu, X. Chen, Y. Zuo, W. Ni, H. Zhang, M. Li, Z. Hu, F. Huang, Y. Cao, T. P. Russell, Z. Liang, M. Zhang, Y. Chen, Over 9% Efficiency of Small Molecule Based Solar Cells with Nanoscale Fibrillar Morphology. Nat. Photon.9, 35-41 (2015).

2. S. Han, L. Hu, Z. Liang, S. Wageh, A. A. Al-Ghamdi, Y. Chen, X. Fang, One-Step Hydrothermal Synthesis of 2D Hexagonal Nanoplates of a-Fe2O3/Graphene Composites with Enhanced Photocatalytic Activity. Adv. Funct. Mater.24, 5719-5727 (2014).

1. X. Chen, B. Wu, Z. He, H. Xuxie, Z. Liang,* X. Hou,* Transient Photovoltage Study on the Dynamics of Excitons and Carriers in Tris-(8-hydroxyquinolinato)aluminum (AlQ). J. Appl. Phys.116, 153704 (2014).

有机功能材料课题组

研究方向:有机功能材料与能源转换,包括能源材料的化学与表征、器件的制备与测试、光热电能量转换过程中的基础研究;中心目标是设法在分子尺度上与器件基础上深度地理解一个宽范围内的功能化材料, 并用在能源转化及储存体系中;这些科研探索既有新能源材料与器件的基础研究, 也着重开发与应用清洁能源的新材料。

现有成员:(1)博士研究生:唐俊晖(复旦大学材料科学系本科)、陈睿思(华中科技大学本科)、谢佳琪(多伦多大学材料工程硕士)、吴致远(武汉理工大学本科);(2)硕士研究生:廖凯(南开大学材料科学与工程学院本科)、朱仁阳(北京科技大学材料科学与工程学院本科)、白雅馨(台北市立大学本科)、马元辰(复旦大学材料科学系本科)。

毕业成员:1.陈亚妮(复旦大学材料系博士)、何岷洪(复旦大学材料系博士)、孙勇(复旦大学材料系硕士)、刘晓宇(复旦大学材料系硕士)、严亚杰(复旦大学材料系博士)、于爽(复旦大学材料系博士)、姬敬敬(复旦大学材料系博士)、王家林(复旦大学材料系博士、现在上海幂方电子科技公司)、彭佳君(复旦大学材料系硕士,现在南京银行上海总行)、孙一婧(复旦大学材料系材料化学专业本科,现在澳大利亚攻读硕士研究生)、高旺(复旦大学材料系材料物理专业本科,现在美国Cornell University攻读硕士研究生)、林小峰(复旦大学材料系物理电子专业本科,现在美国University of Illinois at Urbana-Champaign攻读硕士研究生)、孙璟玮(浙江工业大学化学系博士, 现任湖州师范学院讲师)、陈小青(复旦大学物理系博士,现在日本NIMS博士后)、姚璎珊(复旦大学材料化学专业本科,现在瑞典皇家理工学院攻读硕士研究生)、苏迪清(复旦大学材料物理专业本科,现在美国University of Minnesota, Dept. of Chemical Engineering and Materials Science攻读博士研究生)、陈东生(上海大学物理系博士,在职)、赵艳(复旦大学材料系硕士)。

欢迎本科生、硕士研究生加入本组攻读硕/博!